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Molarity and Dilution Formulas

Molarity formula for solution concentration and the dilution equation.
Includes moles, volume, and dilution examples.

Molarity Formula

M = n / V

where n = mass / molar mass

Molarity (M) is the most common way to express the concentration of a solution. It tells you how many moles of solute are dissolved in one liter of solution.

Dilution Equation

M₁V₁ = M₂V₂

When you dilute a solution (add more solvent), the amount of solute stays the same. This equation lets you find the new concentration or the volume needed.

Variables

SymbolMeaningUnit
MMolarity (concentration)mol/L (M)
nNumber of moles of solutemol
VVolume of solutionLiters (L)
M₁Initial (concentrated) molaritymol/L
V₁Initial volumeL or mL
M₂Final (diluted) molaritymol/L
V₂Final volumeL or mL

Example 1 — Calculating Molarity

You dissolve 58.44 g of NaCl (molar mass = 58.44 g/mol) in water to make 2 L of solution. What is the molarity?

n = mass / molar mass = 58.44 / 58.44 = 1 mol

M = n / V = 1 / 2

M = 0.5 mol/L (0.5 M NaCl solution)

Example 2 — Dilution

You have 100 mL of 6 M HCl. How much water must you add to make a 1 M solution?

M₁V₁ = M₂V₂

6 × 100 = 1 × V₂

V₂ = 600 mL (total final volume)

Add 500 mL of water (600 − 100 = 500 mL)

Example 3 — Finding Moles Needed

How many grams of KOH (molar mass 56.11 g/mol) are needed to make 500 mL of 0.25 M solution?

n = M × V = 0.25 × 0.5 L = 0.125 mol

mass = n × molar mass = 0.125 × 56.11

mass = 7.01 g of KOH


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